T.R | Title | User | Personal Name | Date | Lines |
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470.1 | It may not ever cure | LEDS::WATT | | Thu Feb 11 1988 13:58 | 17 |
| You may have a problem getting it to cure at all if the mix was
that far off. I had this unfortunate experience once when working
on a boat in the winter. My garage was probably at about 55 degrees.
I had to scrape the stuff off and use acetone to clean off the rest.
Epoxy is fairly sensitive to mix ratio because the hardener gets
used up in the reaction instead of acting just as a catylist like
the stuff for polyester does. When all of the hardener reacts,
you're done. If extra heat doesn't do it, it's time to try to get
the stuff off. By the way, most epoxy and polyester does not cure
well below 70-degrees. I have to use a heat lamp to help it along
in the winter because I can't afford to turn the heat in my shop
up to 70-degrees. The lower temp does help pot life though. I
used to pack the polyester resin can in ice when I worked on boats
in hot weather to extend the pot life.
Charlie
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470.2 | OOOOOOPS! YOU DID A NO-NO......... | MAUDIB::CASEYA | THE DESERT RAT (I-RC-AV8) | Thu Feb 11 1988 14:00 | 26 |
| Kay,
You "already" know this [now], but what you did is a no-no with
epoxies. Proper polymerization/curing of the epoxy depends upon
proper mixture of the two-parts. There's an excellent chance that
it'll "never" cure, even give a year or more! Epoxies "do not"
air cure through evaporation of solvents....they cure chemically,
depending on correct proportions of the two agents to cause a
chemical change to a solid and will do this even in a vacuum.
Heat merely accelerates the chemical curing process. Conversely,
cold retards it. But, key to the process is the correct mix....
without this, you may be "dead."
Even allowing a week to see if a miracle might occur, you should be
aware that, even if it does eventually cure, the strength of the
resultant joint might be substandard...I'd hesitate trusting it on
such a critical joint as the wing center-section.
If you still can, I'd separate the wing halves using heat, if
necessary, to fascillitate things, Plain old Isopropyl [bathroom]
alcohol should clean up the residual mess well enough to reglue
it with fresh epoxy...just be sure it doesn't attack the foam - it
shouldn't.
G'luck and let us know how you make out. Adios, Al
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470.3 | AN EPOXY ANALOGY........... | MAUDIB::CASEYA | THE DESERT RAT (I-RC-AV8) | Thu Feb 11 1988 14:17 | 20 |
| Kay,
After entering my reply and reading Charlies, it occurs that a little
more understanding about epoxy might benefit other noters, in addition
to yer'self.
As Charlie intimates, epoxy is NOT a resin and hardener substance
like polyester resins. That's why it's usually labelled part-A
and part-B...each part is integrally/equally important to the chemical
reaction which converts it to a high-strength solid, each containing
half of the required polymers.
The best analogy I've heard compares epoxy to velcro: think of part-A
as being chemical "hooks" and part-B as being chemical "eyes."
If you'll think of it this way it'll be easy to understand why,
even if it "does" cure, an inferior substance will result...you've got
only half as many chemical "hooks" as "eyes" to form the "velcro" so
maximum strength "CANNOT" be achieved!
Adios amigo, Al
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470.4 | Has it cured yet? | CHGV04::KAPLOW | sixteen bit paleontologist | Sun May 01 1988 01:16 | 16 |
| One of the interesting things I've learned about epoxy is that you
can vary the mix slightly, although your 50% is probably too far.
While it isn't surprising that less hardener will take longer to
harden, I was surprised to learn that the result will be harder
than normal. More hardener will speed the reaction, but never get
quite as hard as normal.
Several years ago, I was trying to cast solid parts from polyester
resin. Mixed normally, the parts would crack from the reaction
heat. With half the catalyst it took much longer to harden, but
didn't crack. The resulting castings were very hard, kind of
amber-like, and quite machinable on my lathe. This also works
with materials like Bondo.
In general, it's better to follow the directions, as you've now
learned.
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470.5 | Thinned, it may never set | CHGV04::KAPLOW | sixteen bit paleontologist | Sun May 01 1988 01:20 | 5 |
| One more thing I forgot. Sometimes I thin epoxy resins for
fiberglassing (Kevlaring? it's harder to wet Kevlar than glass). I
use Safe-T-Poxy, which can be thinned with 20-50% isopropol (sp?)
alchohol. If thinned to extreme (50%) the result won't set up in
the pot, but will set in thin films.
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470.6 | a messy nose for a lady | ABACUS::RYDER | perpetually the bewildered beginner | Tue May 01 1990 01:58 | 16 |
| I had decided to replace the nose of a trashed Gentle Lady with foam
and a fiberglass skin. The two epoxy (Locktite 30 minute) bottles
weighed about the same, so I decided for this much quantity to measure
by weight instead of volume; my scale sensitivity is 0.1 ounce, and I
weighed out about 0.4 ounces of each.
After 63 hours of warm sunlight, heat lamps, and other attention, the
fiberglass is still sticky. I suspect I have now _really_ trashed the
Gentle Lady --- this will never harden enough to sand.
Alton, who now wishes he had used polyester resin.
p.s. This note was found in seconds with the technique of note 2.4 and
the Boolean options of the VMS SEARCH command.
Notes> $ SEARCH/MATCH=AND RC11.A fisher,epoxy
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470.7 | the nose has been wiped clean | ABACUS::RYDER | perpetually the bewildered beginner | Fri May 04 1990 08:41 | 20 |
| I've solved my problem. I scrubbed off all of the uncured epoxy and
embedded glass with alcohol, dried it off, and started over. My only
epoxy alternative in the shop was PIC's 4 1/2 minute epoxy, so the
fiberglassing was a bit exciting, but it worked.
I found another note by Kay that was directly applicable. To quote,
"I don't know what the problem was but thanks for reminding me to throw
away two nearly full bottles of Loctite Epoxy. I used this to cover
the surface of my Hobie Hawk after I added some carbon fiber to the tail.
Days later it was still wet. ...... 90-100 degrees for a week or two.
Then .... for a couple weeks .... Then I ignored it for another month.
"I will only use Loctite on screws. They can keep their epoxy."
Loctite is a well respected name in industrial adhesives, but it may be
that the mixing ratio has little leeway or that the shelf life is a
problem. Moreover, two of us have now had horrible experiences with it,
so I for one will try other brands in the future. And for other and
obvious reasons, I will also avoid a fast epoxy for fiberglass layup.
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